Let's see...
In the original XX: Looks like he appears in I-no's path 1 ending, Axl's path 1 ending, and Eddie's path 3 ending.
Been a while since I played the original XX story mode. This is a useful reference if you want to no more about the endings: http://www.gamefaqs.com/ps2/562111-guilty-gear-x2/faqs/27246 (massive spoilers)
As for AC+... I think he appears in the Anji and I-no stories but doesn't reveal any more surprises like he did in Axl's XX story.
Hope this helps!